Anti-Markovnikov hydroarylation of styrenes catalyzed by an in situ generated ruthenium complex.
نویسندگان
چکیده
An efficient and practical catalytic system for the anti-Markovnikov ruthenium-catalyzed hydroarylation of styrenes with acetophenone, allowing a straightforward access to bibenzyl backbones, is described for the first time: this process, involving regioselective C-H bond activation, is complementary to a Friedel-Crafts type reaction giving the branched adduct.
منابع مشابه
The lewis acidic ruthenium-complex-catalyzed addition of beta-diketones to alcohols and styrenes is in fact Brønsted acid catalyzed.
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ورودعنوان ژورنال:
- Chemical communications
دوره 33 شماره
صفحات -
تاریخ انتشار 2008